Investigations on organolead compounds. V. Leadlead bond cleavage reactions of hexaphenyldilead
article
It has been shown that a number of nucleophilic and weakly electrophilic reagents (organolithium and organomagnesium compounds, metallic lithium, potassium permanganate, sodium ethoxide, diaryl disulphides, sulphur, ozone, hypochlorous acid and iodine/iodide) selectively cleave the leadlead bond of hexaphenyldilead. No leadphenyl bond cleavage occurs with these reagents. The reactions with lithium, potassium permanganate, diaryl disulphides, ozone, hypochlorous acid and iodine/iodide form useful synthetic procedures for the preparation of triphenyl-lead derivatives from the readily available hexaphenyldilead. © 1968.
TNO Identifier
227064
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 15(1), pp. 117-124.
Pages
117-124
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