Side-chain liquid-crystalline poly(ketone)s: Effect of spacer length, mesogen type and mesogen density on mesomorphic behavior
article
Novel side-chain liquid-crystalline copolymers (SCLCPs) were synthesized via the Pd(II) catalyzed alternating copolymerization of mesogenic 1-alkenes and carbon monoxide. For methoxybiphenyl mesogens, these copolymers exhibited highly ordered smectic E mesophases and high glass transition temperatures. The transition temperatures of these polymers were tuned by altering the spacer length or by dilution of mesogen-containing alkenes with 1-hexene. Polymers with cyanobiphenyl or methoxyazobenzene mesogens exhibited nematic mesophases. These polymers were the first ever nitrogen containing copolymers of this type. Increase of the spacer length or the 1-hexene content of methoxybiphenyl-containing copolymers resulted in a decrease of the surface polarity of spincoated films. The decomposition temperature of these SCLCPs started far above the isotropization temperature of the polymers. © Wiley-VCH Verlag GmbH, 2000.
TNO Identifier
235880
ISSN
10221352
Source
Macromolecular Chemistry and Physics, 201(17), pp. 2484-2492.
Pages
2484-2492
Files
To receive the publication files, please send an e-mail request to TNO Repository.