Local-scale inversion of agricultural ammonia emissions: a case study on Schiermonnikoog, the Netherlands
article
Quantifying real-world emission reductions is a core goal of atmospheric inversion methods, yet di rect validation against known events remains rare, especially for reactive species like ammonia. In this study, we have applied local-scale Bayesian inversions using ground-based measurements and the LOTOS-EUROS air quality model, with high-resolution emission inventories as prior input, not to explore a theoretical scenario, but to evaluate a documented emission reduction. On the island of Schiermonnikoog in the Netherlands, where GVE (grazing livestock units) decreased from 639 to 541, with a particularly notable reduction in dairy cattle, am monia emissions are expected a 23 % reduction between 2019 and 2022. Our inversion captured a similar trend, estimating a 51 % decrease, which may be overestimated, largely attributed to uncertainties in the 2019 posterior emissions. The posterior for 2022 shows consistency with the validation and indicates a 27 % reduction com pared with the prior emissions of 2019. The associated uncertainty, derived from the posterior error covariance, highlights both the potential of the method and its limitations for policy verification. Moreover, we developed a method to assess the usefulness of individual observations and propose that adding a single high-quality con tinuous measurement in a strategically chosen location can significantly enhance the inversion performance. This strengthens the observational constraint and enhances the system’s ability to resolve temporal variations in emissions.
Topics
TNO Identifier
1020978
Source
Atmospheric Chemistry and Physics(25), pp. 15593-15611.
Pages
15593-15611