Preparation and properties of organo(acetylacetonato)antimony(V) compounds

article
Organo(acetylacetonato)antimony(V) compounds of the types R2SbCl2Acac, R4SbAcac, PhSbCl3Acac and Cl4SbAcac have been synthesized. The compounds are monomeric in solution. IR and PMR data of these compounds, which contain a chelated Acac ligand have been discussed. Ph2SbCl2Acac shows abnormal behaviour, in that in chloroform solution a non-chelated configuration in which the Acac group is probably C-bonded, is also present. © 1969.
Topics
TNO Identifier
227101
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 16(2), pp. 257-263.
Pages
257-263
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