Antimony-121 Mössbauer spectra of six-co-ordinate di- and tri-organoantimony(V) compounds

article





Bertazzi, N.

Di Bianca, F.

Gibb, T.C.

Greenwood, N.N.

Meinema, H.A.

Noltes, J.G.
The 121Sb Mössbauer spectra are reported for a series of organoantimony(V) compounds of the type [SbR3(trid)] and [SbClR 2(trid)] (R = Me or Ph, trid = tridentate ligand with ONO or ONS donor atoms). The compounds have an effective octahedral geometry with a meridionally disposed tridentate ligand and a T-shaped SbR3 or trans-SbR2 moiety. The observed parameters are fully consistent with a simple point-charge interpretation.
TNO Identifier
228255
Repository link
https://resolver.tno.nl/uuid:cca12a7a-5f05-4de1-9a86-884080d3824d
ISSN
14727773
Source
Journal of the Chemical Society, Dalton Transactions(10), pp. 957-959.
Pages
957-959
Files
To receive the publication files, please send an e-mail request to TNO Repository.