The reactivity of small-ring monostannacycloalkanes. III. Ring-expansion reactions of 1,1-dimethyl-1-stannacyclopentane
article
As a result of the enhanced reactivity of the endo-cyclic tincarbon bond 1,1-dimethyl-1-stannacyclopentane readily undergoes ring-expansion reactions with a variety of substrates to produce new organotin heterocycles. Illustrative examples include ring-expansion reactions with oxygen, sulphur, sulphur dioxide, diiron noncarbonyl, dichlorocarbene and diethyl azodicarboxylate. ?? 1979.
TNO Identifier
228658
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 166(3), pp. 339-346.
Pages
339-346
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