Synthesis and crystal structure of the novel transition- metal substituted tin hydride H2Sn2[Mn(CO)5]4
article
Dicyclopentadienyltin reacts with manganese pentacarbonyl hydride to give the first transition-metal substituted ditin dihydride, H[Mn(CO)5]2SnSn- [Mn(CO)5]2H, the structure of which has been determined by X-ray analysis. The compound crystallizes in the monoclinic space group C2 c with four molecules in a unit cell of dimensions = a = 15.71, b = 17.18, c = 12.51 Å and β = 107.3°. Reaction of the dihydride with CCl4 and CBr4 gives Cl2Sn2[Mn(CO)5]4 and Br2Sn2[Mn(CO)5]4, respectively. With acrylonitrile the hydrostannationn product is formed. © 1975.
TNO Identifier
227822
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 92(1), pp. C52-C54.
Pages
C52-C54
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