Studies in group IV organometallic chemistry XXVIII. Structure of products obtained in the hydrostannation of strongly electrophilic carbonyl compounds

article
Organotin monohydrides were brought into reaction with strongly electrophilic carbonyl compounds, yielding mainly 1:1 and 1:2 adducts. The identity of these adducts was established by elementary analysis and NMR spectroscopy. An NMR study of some of the adducts suggests that the absence or presence of 117.119SnOCH coupling in alkoxytin compounds depends on the rate of exchange of the alkoxy groups bound to tin. © 1968.
TNO Identifier
227043
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 13(1), pp. 155-162.
Pages
155-162
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