Stereochemistry of a Michaelis-Arbusov reaction : alkylation of optically active ethyl trimethylsilyl phenylphosphonite with retention of configuration

Berg, G.R. van den; Platenburg, D.H.J.M.; Benschop, H.P.

Stereochemistry of a Michaelis-Arbusov reaction : alkylation of optically active ethyl trimethylsilyl phenylphosphonite with retention of configuration

article

1971

Berg, G.R. van den

Platenburg, D.H.J.M.

Benschop, H.P.

Ethylation of ethyl phenylphosphinate (I) via ethyl trimethylsilyl phenylphosphonite or via the corresponding trimethylstannyl ester, and free-radical addition of (I) to ethylene proceed with complete, or almost complete, retention of configuration.

Topics

Stereochemistry Alkylation Optical activity Phosphorus organic compounds Silicon organic compounds Tin organic compounds Ethylation Chemical reactions Free radicals Addition reactions

TNO Identifier

227293

Repository link

https://resolver.tno.nl/uuid:b419d418-c4d9-4050-a978-517ab0b33fdf

ISSN

05776171

Source

Journal of the Chemical Society D : Chemical Communications(12), pp. 606-607.

Pages

606-607

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Stereochemistry of a Michaelis-Arbusov reaction : alkylation of optically active ethyl trimethylsilyl phenylphosphonite with retention of configuration

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