Inductive effects on benzene solvent shifts in PMR spectra of (acetylacetonato)-organoantimony(V) and bis(acetylacetonato)organotin(IV) compounds
article
PMR benzene solvent shifts (Formula Presented.) and (Formula Presented.) have been measured for acetylacetonato protons of hexacoordinate (acetylacetonato)organoantimony(V) and bis(acetylacetonato)organotin(IV) compounds. The observed values correlate better with the inductive effect of substituents at the metal atom than with the molecular dipole moments of these compounds. It is demonstrated that this relation holds also for tetrahedral compounds. The stereochemistry of the benzene‐acetylacetonato group interaction is discussed
TNO Identifier
355797
Source
Recueil des travaux chimiques des Pays-Bas, 91, pp. 911-922.
Pages
911-922
Files
To receive the publication files, please send an e-mail request to TNO Repository.