Investigations on organogermanium compounds; III. N-tributylgermyl-substituted aliphatic and heterocyclic amines
article
A series of new organogermanium compounds containing a germanium‐nitrogen bond, in many of which the nitrogen atom forms part of an heterocyclic ring, are prepared, in some cases by new methods: transamination reactions and reactions of germoxanes with heterocyclic amines. Striking differences in reactivity towards solvolyzing agents are observed. These are explained by postulating reaction mechanisms in which an important role is assigned to the availability of the electron pair at the nitrogen atom of the germanium‐nitrogen bond
TNO Identifier
355759
Source
Recueil des travaux chimiques des Pays-Bas, 84(9/10), pp. 1597-1609.
Pages
1597-1609
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