Interaction of arylmetal compounds of group 1B with copper(I) and silver(I) trifluoromethanesulphonate; a novel biaryl synthesis and a route to hexanuclear aryl-CuAg, -AgAu, and -CuAu clusters

article


Koten, G. van

Jastrzebski, J.T.B.H.

Noltes, J.G.
Whereas selective biaryl formation is observed when arylcopper compounds 4-MeC6H4Cu, 2-Me2NC6H4Cu, and 2-Me2NCH2C6H4Cu are treated in exact 1:1 molar ratio with (CF3SO3)Cu, reactions of 2-Me2NC6H4M (M = Cu or Au) with (CF 3SO3)Cu (2:1) and of Ar4Au2Li 2 with (CF3SO3)Cu or (CF3SO 3)Ag (1:2) afford novel hexanuclear cluster compounds of the type Ar4M4M′2(CF3SO 3)2.
TNO Identifier
228213
Repository link
https://resolver.tno.nl/uuid:0b2abb7e-6bc8-44a2-99d4-a4ef8870f856
ISSN
00224936
Source
Journal of the Chemical Society, Chemical Communications(7), pp. 203-204.
Pages
203-204
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