Investigations on organozinc compounds IX. Coordination chemistry of organozinc compounds RZnX: organozinc derivatives of tert-butanol, some phenols, diethylhydroxylamine and some oximes
article
The coordination chemistry of organozinc-oxygen derivatives RZnOR′ in which R′ stands for tert-Bu, C6H5, C6Cl5, C6F5, NEt2, NCMePh and NCHPh has been studied. Depending on the nature of R′ such compounds are dimeric (C6Cl5, C6F5), trimeric (tert-Bu), tetrameric (C6H5, NCMePh), hexameric (NEt2), or more highly associated (NCHPh) in benzene solution. Plausible structures have been assigned to these compounds on the basis of spectroscopic (IR, PMR) and molecular weight data. The behaviour of these compounds in the presence of mono- and bidentate ligands is discussed. © 1968.
TNO Identifier
227039
ISSN
0022328X
Source
Journal of Organometallic Chemistry, 12(3), pp. 425-431.
Pages
425-431
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