On the reactivity of organophosphorus compounds. II: The effects of structural variations in the alkyl and alkoxy groups on the values of ΔH* and ΔS* for the alkaline hydrolysis of a number of organophosphorus esters
article
The second-order rate constants of the alkaline hydrolysis at different temperatures of a number of nitrophenyl phosphorus esters and the values of the quantities ΔH* and ΔS* at 25˚C are reported. The effect of structural changes on the values of ΔH* and ΔS* are considered and are compared with similar changes in other nucleophilic substitution reactions, on both phosphorus and carbon atoms.
Topics
TNO Identifier
126684
Source
Recueil des Travaux Chimiques des Pays-Bas, 85(7), pp. 694-700.
Place of publication
Rijswijk
Pages
694-700
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