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Eberbach, M.C. (author), Huinink, H.P. (author), Shkatulov, A.I. (author), Fischer, H.R. (author), Adan, O.C.G. (author)The hydration of salts has gained particular interest within the frame of thermochemical energy storage. Most salt hydrates expand when absorbing water and shrink when desorbing, which decreases the macroscopic stability of salt particles. In addition, the salt particle stability can be compromised by a transition to an aqueous salt solution,...article 2023
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Figueiredo, D.M. (author), Vermeulen, R.C.H. (author), Jacobs, C. (author), Holterman, H.J. (author), van de Zande, J.C. (author), van den Berg, F. (author), Gooijer, Y.M. (author), Lageschaar, L. (author), Buijtenhuijs, D. (author), Krop, E. (author), Huss, A. (author), Duyzer, J.H. (author)Background Pesticides can be transported from the site of application to homes via different routes and lead to exposure of residents, raising concerns regarding health effects. We built a deterministic model framework (OBOmod) to assess exposure of residents living near fields where pesticides are applied. Methods OBOmod connects five...article 2022
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Houben, J. (author), Langelaan, D. (author), Brinkman, L. (author), Huinink, H. (author), Fischer, H.R. (author), Adan, O.C.G. (author)In this work, the relation between mobility and metastability is investigated. This is done under pure water vapor vacuum conditions. First, the properties of the metastable zone under pure water vapor conditions are investigated and compared to those under atmospheric conditions. Second, mobility is investigated using electrochemical impedance...article 2022
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Mazur, N. (author), Huinink, H. (author), Borm, B. (author), Sansota, S. (author), Fischer, H. (author), Adan, O. (author)This work studied the reversible dehydration of potassium carbonate sesquihydrate (K2CO3·1.5H2O). The study is based on isobaric and isothermal thermogravimetric measurements conducted at a broad range of vapour pressures and temperatures. By controlling both parameters, we examined the influence of both constraints on the reaction kinetics at a...article 2022
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- Melskens, J. (author), Theeuwes, R.J. (author), Black, L.E. (author), Berghuis, W.J.H. (author), Macco, B. (author), Bronsveld, P.C.P. (author), Kessels, W.M.M. (author) article 2021
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- Grillo, F. (author), Soethoudt, J. (author), Marques, E.A. (author), de Martin, L. (author), van Dongen, K. (author), van Ommen, J.R. (author), Delabie, A. (author) article 2020
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van Kampen, J. (author), Boon, J. (author), van Berkel, F.P.F. (author), Vente, J.F. (author), van Sint Annaland, M. (author)Enhancement by steam separation is a promising process intensification for many types of reactions in which water is formed as a byproduct. For this, two main technologies are reactive vapor permeation (membrane technology) and reactive adsorption. Both can achieve significant conversion enhancement of equilibrium limited reactions by in situ...article 2019
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Goede, H.A. (author), McNally, K. (author), Gorce, J.P. (author), Marquart, H. (author), Warren, N.D. (author), Fransman, W. (author), Tischer, M. (author), Schinkel, J. (author)This article describes the development of a mechanistic model for underpinning the dermal Advanced REACH Tool (dART), an extension of the existing ART model and its software platform. It was developed for hand exposure to low volatile liquids (vapour pressure ≤ 10 Pa at 20°C) including solids-in-liquid products. The model is based on an existing...article 2019
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van Kampen, J. (author), Boon, J. (author), van Berkel, F.P.F. (author), Vente, J.F. (author), van Sint Annaland, M. (author)Enhancement by steam separation is a promising process intensification for many types of reactions in which water is formed as a byproduct. For this, two main technologies are reactive vapor permeation (membrane technology) and reactive adsorption. Both can achieve significant conversion enhancement of equilibrium limited reactions by in situ...article 2019
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Blanker, J. (author), Vroon, Z.A.E.P. (author), Zeman, M. (author), Smets, A. (author)Copper-indium-gallium-di-selenide (CIGS) is the present record holder in lab-scale thin-film photovoltaics (TF-PV). One of the problems of this PV technology is the scarcity of indium. Multi-junction solar cells allow better spectral utilization of the light spectrum, while the required current generation per layer is much lower, allowing much...conference paper 2018
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Erkens, I.J.M. (author), Verheijen, M.A. (author), Knoops, H.C.M. (author), Keuning, W. (author), Roozeboom, F. (author), Kessels, W.M.M. (author)To date, conventional thermal atomic layer deposition (ALD) has been the method of choice to deposit high-quality Pt thin films grown typically from (MeCp)PtMe3 vapor and O2 gas at 300 °C. Plasma-assisted ALD of Pt using O2 plasma can offer several advantages over thermal ALD, such as faster nucleation and deposition at lower temperatures. In...article 2017
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Blanker, J. (author), Vroon, Z. (author), Zeman, M. (author), Smets, A. (author)Copper-indium-gallium-di-selenide (CIGS) is the present record holder in lab-scale thin-film photovoltaics (TFPV). One of the problems of this PV technology is the scarcity of indium. Multi-junction solar cells allow better spectral utilization of the light spectrum, while the required current generation per layer is much lower, allowing much...conference paper 2016
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van de Burgt, Y. (author), van Loon, W. (author), Mandamparambil, R. (author), Bellouard, Y. (author)The localized growth of carbon nanotube structures has potential in many applications such as interconnects, field emitters and sensors. Using a laser to locally heat the substrate offers a highly versatile process compatible with a broad range of substrates and devices. However, for laser-assisted CNT growth, detailed process information, such...article 2014
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Van Assche, F.J.H. (author), Unnikrishnan, S. (author), Michels, J.J. (author), van Mol, A.M.B. (author), van de Weijer, P. (author), van de Sanden, M.C.M. (author), Creatore, M. (author)We report on a low substrate temperature (110°C) remote microwave plasma-enhanced chemical vapor deposition (PECVD) process of silicon nitride barrier layers against moisture permeation for organic light emitting diodes (OLEDs) and other moisture sensitive devices such as organic photovoltaic cells (OPVs). Specifically, the influence of the SiH4...article 2014
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High-throughput processes for industrially scalable deposition of zinc oxide at atmospheric pressureIlliberi, A. (author), Grob, F. (author), Kniknie, B. (author), Frijters, C. (author), van Deelen, J. (author), Poodt, P. (author), Beckers, E.H.A. (author), Bolt, P.J. (author)ZnO films have been grown on a moving glass substrate by high temperature (480 0C) chemical vapour deposition (CVD) and low temperature (200 0C) plasma enhanced CVD (PE-CVD) process at atmospheric pressure. Deposition rates above 7 nm/s have been achieved for substrate speeds from 20 to 500 mm/min. The conductivity of the films is enhanced by Al...article 2014
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Khakharia, P.M. (author), Kvamsdal, H.M. (author), Da Silva, E.F. (author), Vlugt, T.J.H. (author), Goetheer, E.L.V. (author)Emission of solvent and its degradation products from a typical absorption-desorption based Post Combustion CO2 Capture (PCCC) process is inevitable and thus, an area of growing concern. Recently, it has been pointed out that emissions can also occur by means of aerosol droplets. Conventional counter-measures such as a water wash and a demister...article 2014
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Michels, J.J. (author), Peter, M. (author), Salem, A. (author), van Remoortere, B. (author), van den Brand, J. (author)This paper presents a thorough experimental and theoretical analysis of a model system for the mechanism of cathode degradation in OLED and OPV devices due to lateral side ingress of water vapour into laminated thin film barrier structures. The experimental procedure allows for full quantitative control over layer dimensions of the laminate, as...article 2014
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van de Burgt, Y. (author)Laser-assisted chemical vapor deposition (LACVD) is an attractive maskless process for growing locally carbon nanotubes at selected places on substrates that may contain temperature-sensitive components. This review gives a comprehensive overview of the reported research with respect to laser assisted CVD for the growth of carbon nanotubes. The...article 2014
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van de Burgt, Y. (author), Bellouard, Y. (author), Mandamparambil, R. (author)Laser-assisted chemical vapour deposition (CVD) growth is an attractive mask-less process for growing locally aligned carbon nanotubes (CNTs) in selected places on temperature sensitive substrates. The nature of the localized process results in fast carbon nanotube growth with high experimental throughput. Here, we report on the detailed...article 2014
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Illiberi, A. (author), Grob, F. (author), Frijters, C. (author), Poodt, P. (author), Ramachandra, R. (author), Winands, H. (author), Simor, M. (author), Bolt, P.J. (author)Undoped zinc oxide (ZnO) films have been grown on a moving glass substrate by plasma-enhanced chemical vapor deposition at atmospheric pressure. High deposition rates of ∼7 nm/s are achieved at low temperature (200°C) for a substrate speed from 20 to 60 mm/min. ZnO films are highly transparent in the visible range (90%). By a short (∼minute)...article 2013