Kinetic measurements and in situ Raman spectroscopy study of the formation of TBAF semi-hydrates with hydrogen and carbon dioxide

The kinetics of formation of semi-clathrate hydrates of tetra n-butyl ammonium fluoride (TBAF) with hydrogen (H2) and carbon dioxide (CO2) were studied in order to elucidate their potential for H 2 storage as well as for CO2 sequestration. The influence of pressure, TBAF concentration (1.8 mol% and 3.4 mol%) and formation method (T-cycle method...