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Houben, J. (author), Langelaan, D. (author), Brinkman, L. (author), Huinink, H. (author), Fischer, H.R. (author), Adan, O.C.G. (author)In this work, the relation between mobility and metastability is investigated. This is done under pure water vapor vacuum conditions. First, the properties of the metastable zone under pure water vapor conditions are investigated and compared to those under atmospheric conditions. Second, mobility is investigated using electrochemical impedance...article 2022
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Mazur, N. (author), Huinink, H. (author), Borm, B. (author), Sansota, S. (author), Fischer, H. (author), Adan, O. (author)This work studied the reversible dehydration of potassium carbonate sesquihydrate (K2CO3·1.5H2O). The study is based on isobaric and isothermal thermogravimetric measurements conducted at a broad range of vapour pressures and temperatures. By controlling both parameters, we examined the influence of both constraints on the reaction kinetics at a...article 2022
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Sogütoglu, L.C. (author), Steiger, M. (author), Houben, J. (author), Biemans, D. (author), Fischer, H.R. (author), Donkers, P.A.J. (author), Huinink, H. (author), Adan, O.C.G. (author)The solid-state hydration of salts has gained particular interest within the frame of thermochemical energy storage. In this work, the water vapor pressure-temperature (p-T) phase diagram of the following thermochemical salts was constructed by combining equilibrium and nonequilibrium hydration experiments: CuCl 2 , K 2 CO 3 , MgCl 2 ·4H 2 O,...article 2019