A thorough investigation of thermochemical heat storage system from particle to bed scale

Salt hydrates are promising candidates for the long-term thermochemical heat storage (TCES) in thebuilding environment. In such storage systems, the surplus of energy will be exploited in an endothermicreaction to dehydrate the salt hydrates. Once it is demanded, the stored energy will be released throughan exothermic reaction by hydrating the...

Comparison of structured adsorbents for theadsorptive isolation of food ingredients from largestreams

We present guidelines for the configuration of industrial scale chromatographic separationof small molecules. We compared the performance of different axial packed beds, chan-neled monoliths and a continuous monolith assuming silica as base material. The calculatedmass transfer rates were used to calculate the height of a theoretical plate (HETP...

CLC in packed beds using syngas and CuO/Al2O3: Model description and experimental validation

The objective of this work is to study the performance of the oxygen carrier in a packed bed with periodic switching between oxidizing and reducing conditions. In this paper the performance of CuO/Al2O3 as the oxygen carrier in a packed bed reactor with syngas as the fuel are investigated, while also studying the (possible) carbon deposition and...

Modelling spontaneous ignition of wood, char and RDF in a lab-scale packed bed

Many municipal waste combustors use preheated primary air in the first zone to dry the waste. In most cases the preheat temperature does not exceed 140°C. In previous experiments it is found that at temperatures around 200°C, in some circumstances, self- or spontaneous ignition can be achieved. Using preheated air can be a powerful tool to...

A novel reactor configuration for packed bed chemical-looping combustion of syngas

This study reports on the application of chemical looping combustion (CLC) in pressurized packed bed reactors using syngas as a fuel. High pressure operation of CLC in packed bed has a different set of challenges in terms of material properties, cycle and reactor design compared to fluidized bed operation. However, high pressure operation allows...

Modelling piloted ignition of wood and plastics

To gain insight in the startup of an incinerator, this article deals with piloted ignition. A newly developed model is described to predict the piloted ignition times of wood, PMMA and PVC. The model is based on the lower flammability limit and the adiabatic flame temperature at this limit. The incoming radiative heat flux, sample thickness and...

Spontaneous ignition of wood, char and RDF in a lab scale packed bed

Many municipal waste combustors use preheated primary air in the first zone to dry the waste. In most cases the preheat temperature does not exceed 140 °C. In previous experiments it is found that at temperatures around 200 °C, in some circumstances, self- or spontaneous ignition can be achieved. Using preheated air can be a powerful tool to...

Commercialisation BIVKIN-based gasification technology: non-confidential version

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Elimination of alkanes from off-gases using biotrickling filters containing two liquid phases

Biological techniques are highly cost-effective for the treatment of off-gases containing low concentrations of pollutants (<5 g/m3). They may also be attractive for the elimination of higher concentrations of explosive hydrocarbons (when compared to incineration). Conventional techniques such as biofilters have low elimination capacities for...

Transformation of carbon tetrachloride in an anaerobic packed-bed reactor without addition of another electron donor

Carbon tetrachloride (52 μM) was biodegraded for more than 72% in an anaerobic packed-bed reactor without addition of an external electron donor. The chloride mass balance demonstrated that all carbon tetrachloride transformed was completely dechlorinated. Chloroform and dichloromethane were sometimes also found as transformation products, but...