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Rodriguez-Illera, M. (author), Boon, M.A. (author), Boom, R.M. (author), Janssen, A.E.M. (author)We present guidelines for the configuration of industrial scale chromatographic separationof small molecules. We compared the performance of different axial packed beds, chan-neled monoliths and a continuous monolith assuming silica as base material. The calculatedmass transfer rates were used to calculate the height of a theoretical plate (HETP...article 2015
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Atuonwu, J.C. (author), van Straten, G. (author), van Deventer, H.C. (author), van Boxtel, A.J.B. (author)This work analyzes the synergy between two complementary unit operations - adsorbent dehumidification and drying - and presents a mixed integer nonlinear programming approach to optimize energy performance in a two-stage system. Combined with active constraint analysis, the adsorbent properties that promote energy performance are derived....article 2013
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Offermans, P. (author), Vitushinsky, R. (author), Crego-Calama, M. (author), Brongersma, S.H. (author)AlGaN/GaN shows great promise as a generic platform for (bio-)chemical sensing because of its robustness and intrinsic sensitivity to surface charge or dipoles. Here, we employ the two-dimensional electron gas (2DEG) formed at the interface of AlGaN/GaN layers grown on Si substrates for the ultra-sensitive detection of NOx. In the presence of...conference paper 2011
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Kudryavtsev, Y.V. (author), Gelinck, E.R.M. (author), Fischer, H.R. (author), TNO Industrie en Techniek (author)A theoretical investigation of van der Waals forces acting between two solid silicon surfaces at separations from zero to approximately 20 nm is presented. We focused our efforts on the analysis of different factors that can cause deviations from the classical pressure-distance dependence p ∼ 1/D3. It is demonstrated that a layer (oxide or water...article 2009
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Wijntje, R. (author), Bosch, H. (author), de Haan, A.B. (author), Bussmann, P.J.T. (author), TNO Kwaliteit van Leven TNO Bouw en Ondergrond (author)In prior work we studied the adsorption of triglycine on zeolite Y under reference conditions. This study aims to solve the question of which adsorbent properties and process conditions influence the adsorption triglycine from an aqueous solution by zeolite Y. Relevant zeolite parameters to study are: the amount of acidic sites (Si/Al2 ratio),...article 2007
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Vente, J.A. (author), Bosch, H. (author), de Haan, A.B. (author), Bussman, P.J.T. (author), TNO Kwaliteit van Leven (author)The goal of this work was to enchance the selectivity of the separation of fructose or glucose from carbohydrate mixtures with adsorbents capable of reversible reaction. The experimental data presented demonstrate the feasibility of separating glucose from trans-galacto-oligosaccharides and fructose from fructo-oligosaccharides using resins as...article 2006
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Avantaggiato, G. (author), Havenaar, R. (author), Visconti, A. (author), TNO Voeding (author)In vitro screening of 14 adsorbent materials, including some commercial products used to detoxify Fusarium-mycotoxins, were tested in the pH range of 3-8 for deoxynivalenol (DON)- and nivalenol (NIV)-binding ability. Only activated carbon showed to be effective with binding capacities of 35.1 μmol and 8.8 μmol DON and NIV/g adsorbent,...article 2004
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Avantaggiato, G. (author), Havenaar, R. (author), Visconti, A. (author), TNO Voeding (author)A novel approach is presented herein to study the intestinal absorption of mycotoxins by using a laboratory model that mimics the metabolic processes of the gastrointestinal (GI) tract of healthy pigs. This model was used to evaluate the small-intestinal absorption of zearalenone from contaminated wheat (4.1 mg/kg) and the effectiveness of...article 2003
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Diederen, A.M. (author), van Zee, G. (author), Veenman, A.W. (author), de Graauw, J. (author), Prins Maurits Laboratorium TNO (author)This paper discusses a technical feasibility study on continuous countercurrent sorption equipment using mechanically transported fibrous sorbent materials such as fiber beds and open-cell foam. A pilot unit was developed and tested and the apparatus performed adequately. Under the conditions applied, the separation efficiency of the appartus is...article 1998
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Somers, W.A.C. (author), Koenen, P.H.M. (author), Rozie, H.J. (author), Visser, J. (author), Rombouts, F.M. (author), van 't Riet, K. (author), Centraal Instituut voor Voedingsonderzoek TNO (author)The isolation and purification of α-amylase from an industrial enzyme sample is described using crosslinked starch powder as an affinity adsorbent. The process was studied with regard to the stability of the adsorbent, the stability of the enzyme, and the capacity of the adsorbent for the enzyme. The adsorbent was used in a repeated adsorption...article 1995