Estimation of OH in urban plumes using TROPOMI-inferred NO2/CO

A new method is presented for estimating urban hydroxyl radical (OH) concentrations using the downwind decay of the ratio of nitrogen dioxide over carbon monoxide column-mixing ratios (XNO2/XCO) retrieved from the Tropospheric Monitoring Instrument (TROPOMI). The method makes use of plumes simulated by the Weather Research and Forecast model ...

Quantifying burning efficiency in megacities using the NO2/CO ratio from the Tropospheric Monitoring Instrument (TROPOMI)

This study investigates the use of co-located nitrogen dioxide (NO2) and carbon monoxide (CO) retrievals from the TROPOMI satellite to improve the quantification of burning efficiency and emission factors (EFs) over the megacities of Tehran, Mexico City, Cairo, Riyadh, Lahore, and Los Angeles. Efficient combustion is characterized by high NOx ...

Impact of a future H2 transportation on atmospheric pollution in Europe

Hydrogen (H2) is being explored as a fuel for passenger vehicles; it can be used in fuel cells to power electric motors or burned in internal combustion engines. In order to evaluate the potential influence of a future H2-based road transportation on the regional air quality in Europe, we implemented H2 in the atmospheric transport and chemistry...

Simulation of tropospheric chemistry and aerosols with the climate model EC-Earth

We have integrated the atmospheric chemistry and transport model TM5 into the global climate model EC-Earth version 2.4. We present an overview of the TM5 model and the two-way data exchange between TM5 and the IFS model from the European Centre for Medium-Range Weather Forecasts (ECMWF), the atmospheric general circulation model of EC-Earth. In...

Reassessing the variability in atmospheric H2 using the two-way nested TM5 model

This work reassesses the global atmospheric budget of H2 with the TM5 model. The recent adjustment of the calibration scale for H2 translates into a change in the tropospheric burden. Furthermore, the ECMWF Reanalysis-Interim (ERA-Interim) data from the European Centre for Medium-Range Weather Forecasts (ECMWF) used in this study show slower...

A large-eddy simulation of the phase transition of ammonium nitrate in a convective boundary layer

Under warm and dry conditions, ammonium nitrate aerosol outgasses to form ammonia and nitric acid in the lower atmospheric boundary layer. In the upper boundary layer, where the temperature is lower and the relative humidity is higher, nitric acid and ammonia condense back to the aerosol phase. Measurements show that aerosol nitrate mixing...

Reassessing the variability in atmospheric H2 using 1, Journal of Geophysical Research

Since the industrialisation of fuel cell technology during the 1970s and 80s, molecu3 3 lar hydrogen (H2) has been considered as a clean alternative for fossil fuel based energy 34 carriers. The selective oxidation of H2 by oxygen only produces water, contrary to the 35 combustion of fossil fuels with air that produces carbon dioxide, carbon...

Modelling the partitioning of ammonium nitrate in the convective boundary layer

Abstract. An explanatory model study is presented on semi-volatile secondary inorganic aerosols on three clear days in May 2008 during the IMPACT campaign at the Cabauw tower in the Netherlands. A single column model in combination with the equilibrium aerosol model ISORROPIA is used. This model uses surface observations from IMPACT and...

The European aerosol budget in 2006

This paper presents the aerosol budget over Europe in 2006 calculated with the global transport model TM5 coupled to the size-resolved aerosol module M7. Comparison with ground observations indicates that the model reproduces the observed concentrations quite well with an expected slight underestimation of PM10 due to missing emissions (e.g....

Modelling the partitioning of ammonium nitrate in the convective boundary layer

An explanatory model study is presented on semi-volatile secondary inorganic aerosols on three clear days in May 2008 during the IMPACT campaign at the Cabauw tower in the Netherlands. A single column model in combination with the equilibrium aerosol model ISORROPIA is used. This model uses surface observations from IMPACT and calculates the gas...

Importance of fossil fuel emission uncertainties over Europe for CO2 modeling: model intercomparison

Inverse modeling techniques used to quantify surface carbon fluxes commonly assume that the uncertainty of fossil fuel CO2 (FFCO2) emissions is negligible and that intra-annual variations can be neglected. To investigate these assumptions, we analyzed the differences between four fossil fuel emission inventories with spatial and temporal...

Inverse modelling of European N2O emissions: assimilating observations from different networks

We describe the setup and first results of an inverse modelling system for atmospheric N2O, based on a four-dimensional variational (4DVAR) technique and the atmospheric transport zoom model TM5. We focus in this study on the European domain, utilizing a comprehensive set of quasi-continuous measurements over Europe, complemented by N2O...

Inverse modeling of European CH4 emissions 2001–2006

European CH4 emissions are estimated for the period 2001–2006 using a fourdimensional variational (4DVAR) inverse modeling system, based on the atmospheric zoom model TM5. Continuous observations are used from various European monitoring stations, complemented by European and global flask samples from the NOAA/ESRL network. The available...

Importance of fossil fuel emission uncertainties over Europe for CO2 modeling: model intercomparison

Inverse modeling techniques used to quantify surface carbon fluxes commonly assume that the uncertainty of fossil fuel CO2 (FFCO2) emissions is negligible and that intraannual variations can be neglected. To investigate these assumptions, we analyzed the differences between four fossil fuel emission maps with spatial and temporal differences...

TransCom model simulations of hourly atmospheric CO2: Experimental overview and diurnal cycle results for 2002

A forward atmospheric transport modeling experiment has been coordinated by the TransCom group to investigate synoptic and diurnal variations in CO2. Model simulations were run for biospheric, fossil, and air-sea exchange of CO2 and for SF6 and radon for 2000–2003. Twenty-five models or model variants participated in the comparison. Hourly...