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Burgers, I. (author), Pérez Gallent, E. (author), Goetheer, E.L.V. (author), Kortlever, R. (author)Aqueous electrolytes are most commonly used for the CO2 reduction reaction (CO2RR), but suffer from a low CO2 solubility that limits the reaction. Electrochemical CO2 reduction in nonaqueous electrolytes can provide a solution, due to the higher CO2 solubility of organic solvent-based electrolytes. Herein, the product distribution of the...article 2023
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Ros, J.A. (author), Skylogianni, E. (author), Doedée, V. (author), van den Akker, J.T. (author), Vredeveldt, A.W. (author), Linders, M.J.G. (author), Goetheer, E.L.V. (author), Garcia Moretz-Sohn Monteiro, J. (author)The International Maritime Organization has set clear objectives towards drastically reducing greenhouse gas emissions the coming decades in the maritime sector. While different ways to reduce emissions are already proposed, these are not expected to generate high CO2 abatement rates (in the case of fuel saving measures) or to be available and...article 2022
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Boor, V. (author), Frijns, J.E.B.M. (author), Perez-Gallent, E. (author), Giling, E. (author), Laitinen, A.T. (author), Goetheer, E.L.V. (author), van den Broeke, L.J.P. (author), Kortlever, R. (author), de Jong, W. (author), Moultos, O.A. (author), Vlugt, T.J.H. (author), Ramdin, M. (author)We performed H-cell and flow cell experiments to study the electrochemical reduction of CO2 to oxalic acid (OA) on a lead (Pb) cathode in various nonaqueous solvents. The effects of anolyte, catholyte, supporting electrolyte, temperature, water content, and cathode potential on the Faraday efficiency (FE), current density (CD), and product...article 2022
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Ros, J.A. (author), Garcia Moretz-Sohn Monteiro, J. (author), Goetheer, E.L.V. (author), Neerup, R. (author), Gong, W. (author), Vinjarapu, S.H.B. (author), Jorsboe, J.K. (author), Nis Bay Villadsen, S. (author), Loldrup Fosbol, P. (author)This chapter presents discussion of four selected case studies for sustainable carbon capture. The first case study is a high-level techno-economic integration study for CO2 capture in the waste to energy (WtE) sector, which may result in negative emissions, as a large part of the CO2 is biogenic. Integration of CO2 capture in this sector is...bookPart 2022
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Ros, J.A. (author), Doedée, V. (author), van den Akker, J.T. (author), Vredeveldt, A.W. (author), Linders, M.J.G. (author), Goetheer, E.L.V. (author), Garcia Moretz-Sohn Monteiro, J. (author)The maritime industry has set clear objectives towards reducing greenhouse gas emissions in the coming decades. Ship based carbon capture (SBCC) could play a large role in reducing these emissions on the short term. This study gives an update on the work that has been conducted towards carbon capture and storage on LNG fuelled vessels. This is...conference paper 2021
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Pérez Gallent, E. (author), Vankani, C. (author), Anastasopol, A. (author), Goetheer, E.L.V. (author)Carbon dioxide (CO2) is currently considered as a waste material due to its negative impact on the environment. However, it is possible to create value from CO2 by capturing and utilizing it as a building block for commodity chemicals. Electrochemical conversion of CO2 has excellent potential for reducing greenhouse gas emissions and reaching...article 2021
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Moser, P. (author), Wiechers, G. (author), Schmidt, S. (author), Garcia Moretz-Sohn Monteiro, J. (author), Goetheer, E.L.V. (author), Charalambous, C. (author), Saleh, A. (author), van der Spek, M. (author), Garcia, S. (author)After a 13,000-hour test campaign with aqueous 30 wt% MEA (2-aminoethanol) solvent at the CO2 capture pilot plant at Niederaussem, another long-term test was carried out as part of the ALING-CCUS project. This test ran for more than 12,275 hours with aqueous AMP/PZ (2-Amino-2-methyl-1-propanol/piperazine) solvent, named CESAR1 (3.0 molar AMP (~...conference paper 2021
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Leal Pérez, B.J. (author), Medrano Jiménez, J.A. (author), Bhardwaj, R. (author), Goetheer, E.L.V. (author), van Sint Annaland, M. (author), Gallucci, F. (author)Nowadays, nearly 50% of the hydrogen produced worldwide comes from Steam Methane Reforming (SMR) at an environmental burden of 10.tCO2,eq/tH2 accelerating the consequences of global warming. One way to produce clean hydrogen is via methane pyrolysis using melts of metals and salts. Compared to SMR, significant less CO2 is produced due to...article 2021
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Buvik, V. (author), Bernhardsen, I.M. (author), Figueiredo, R.V. (author), Vevelstad, S.J. (author), Goetheer, E.L.V. (author), van Os, P.J. (author), Knuutila, H.K. (author)This work aims to understand oxygen solubility in pure and aqueous amine solvents for CO2 capture. Commercially available dissolved oxygen sensors were studied to evaluate whether these can be used for measuring oxygen solubility in the carbon capture processes. It also aims to understand the possible discrepansies from realistic concentrations...article 2021
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Veronezi Figueiredo, R. (author), Srivastava, T. (author), Skaar, T. (author), Warning, N. (author), Gravesteijn, P. (author), van Os, P.J. (author), Ansaloni, L. (author), Deng, L. (author), Knuutila, H. (author), Garcia Moretz-Sohn Monteiro, J. (author), Goetheer, E.L.V. (author)One of the major issues encountered in the Post Combustion CO2 Capture processes is the degradation of the solvent which can be in great part attributed to the presence of oxygen in the solution. The present report focuses on the demonstration of DORA (Dissolved Oxygen Removal Apparatus), a technology developed by TNO as a counter-measure of...article 2021
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Garcia, A.C. (author), Sánchez Martínez, C. (author), Bakker, I.J. (author), Goetheer, E.L.V. (author)Herein, we describe a study of the electrochemical reduction of oxalic and glyoxylic acids toward a feasible green and sustainable production of tartaric acid in aqueous and/or acetonitrile solvent using silver and lead electrodes. Our results show that on the silver electrode, for both oxalic acid and glyoxylic acid, the reduction reaction is...article 2020
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Overcoming Mass Transport Limitations in Electrochemical Reactors with a Pulsating Flow ElectrolyzerPérez Gallent, E. (author), Sánchez Martínez, C. (author), Geers, L.F.G. (author), Turk, S. (author), Latsuzbaia, R. (author), Goetheer, E.L.V. (author)Electrochemical processes are a promising technology for industrial production of chemicals. One of the major drawbacks of electrochemical systems is the low mass transfer of reactants toward the active surface area of the electrode. In this paper, an approach is presented to enhance the mass transfer and increase the overall performance of the...article 2020
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Bisselink, R.J.M. (author), Crockatt, M. (author), Zijlstra, M. (author), Bakker, I.J. (author), Goetheer, E.L.V. (author), Slaghek, T.M. (author), van Es, D.S. (author)The electrochemical production of valeric acid from the renewable bio-based feedstock levulinic acid has the potential to replace the oxo-process, which uses fossil-based feedstock 1-butylene. The electrochemical reduction of the ketone functionality in levulinic acid using lead or mercury cathodes has already been known for over 100 years....article 2019
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Feenstra, M.S. (author), Monteiro, J. (author), van den Akker, J.T. (author), Abu-Zahra, M.R.M. (author), Gilling, E. (author), Goetheer, E.L.V. (author)Total shipping carbon emissions were approximately 938 million tonnes CO 2 in 2012. Zero emission shipping options rely on the use of electricity or alternative fuels, such as blue hydrogen or ammonia. However, that requires major modifications to the ships and the logistics of fuel distribution. As a transition solution, which can be...article 2019
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Pérez-Gallent, E. (author), Turk, S. (author), Latsuzbaia, R. (author), Bhardwaj, R. (author), Anastasopol, A. (author), Sastre-Calabuig, F. (author), Garcia, A.C. (author), Giling, E.J.M. (author), Goetheer, E.L.V. (author)In industrial electrochemical processes it is of paramount importance to achieve efficient, selective processes to produce valuable chemicals while minimizing the energy input. Although the electrochemical reduction of CO2 has received a lot of attention in the past decades, an economically feasible process has not yet been developed. Typically,...article 2019
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Sodiq, A. (author), Hadri, N.E. (author), Goetheer, E.L.V. (author), Abu-Zahra, M.R.M. (author)The present study has established the direct pseudo–first-order reaction kinetics of different aqueous-based single and blended amines over the temperature range of 298.15-313.15 K using stopped-flow techniques. The single amines include one primary amine (monoethanolamine, MEA), two secondary amines (diethanolamine, DEA and 2-ethyl(amino...article 2018
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Dhingra, S. (author), Khakharia, P. (author), Rieder, A. (author), Cousins, A. (author), Reynolds, A. (author), Knudsen, J. (author), Andersen, J. (author), Irons, R. (author), Mertens, J. (author), Zahra, M.A. (author), van Os, P. (author), Goetheer, E.L.V. (author)Oxidative degradation is a serious concern for upscaling of amine-based carbon capture technology. Different kinetic models have been proposed based on laboratory experiments, however the kinetic parameters included are limited to those relevant for a lab-scale system and not a capture plant. Besides, most of the models fail to recognize the...article 2017
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- Hartono, A. (author), Kim, I. (author), Knuutila, H.K. (author), van der Ham, L.V. (author), Goetheer, E.L.V. (author) article 2017
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Rieder, A. (author), Dhingra, S. (author), Khakharia, P.M. (author), Zangrilli, L. (author), Schallert, B. (author), Irons, R. (author), Unterberger, S. (author), van Os, P.J. (author), Goetheer, E.L.V. (author)Degradation of amines is one of the most important issues to be addressed for absorption-desorption based post-combustion CO2 capture. Several laboratory studies have been performed to identify the degradation products and understand the mechanisms of degradation. However, there seems to be a gap in knowledge from translating the lab scale...article 2017
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Mertens, J. (author), Khakharia, P.M. (author), Rogiers, P. (author), Blondeau, J. (author), Lepaumier, H. (author), Goetheer, E.L.V. (author), Schallert, B. (author), Schaber, K. (author), Moretti, I. (author)This study presents the results of two field tests that aimed at evaluating two countermeasures (WESP and GGH) toavoid acid mist formation. A WESP is shown to be very efficient for the removal of nuclei from the flue gas (100 % efficient) and thus can prevent aerosol formation inside an amine based absorber. This is however only valid in the...article 2017