Title
Physicochemical characterization of titanium dioxide pigments using various techniques for size determination and asymmetric flow field flow fractionation hyphenated with inductively coupled plasma mass spectrometry
Author
Helsper, J.P.F.G.
Peters, R.J.B.
van Bemmel, M.E.M.
Rivera, Z.E.H.
Wagner, S.
von der Kammer, F.
Tromp, P.C.
Hofmann, T.
Weigel, S.
Publication year
2016
Abstract
Seven commercial titanium dioxide pigments and two other well-defined TiO2 materials (TiMs) were physicochemically characterised using asymmetric flow field flow fractionation (aF4) for separation, various techniques to determine size distribution and inductively coupled plasma mass spectrometry (ICPMS) for chemical characterization. The aF4-ICPMS conditions were optimised and validated for linearity, limit of detection, recovery, repeatability and reproducibility, all indicating good performance. Multi-element detection with aF4-ICPMS showed that some commercial pigments contained zirconium co-eluting with titanium in aF4. The other two TiMs, NM103 and NM104, contained aluminium as integral part of the titanium peak eluting in aF4. The materials were characterised using various size determination techniques: retention time in aF4, aF4 hyphenated with multi-angle laser light spectrometry (MALS), single particle ICPMS (spICPMS), scanning electron microscopy (SEM) and particle tracking analysis (PTA). PTA appeared inappropriate. For the other techniques, size distribution patterns were quite similar, i.e. high polydispersity with diameters from 20 to >700 nm, a modal peak between 200 and 500 nm and a shoulder at 600 nm. Number-based size distribution techniques as spICPMS and SEM showed smaller modal diameters than aF4-UV, from which mass-based diameters are calculated. With aF4-MALS calculated, light-scattering-based “diameters of gyration” (Øg) are similar to hydrodynamic diameters (Øh) from aF4-UV analyses and diameters observed with SEM, but much larger than with spICPMS. A Øg/Øh ratio of about 1 indicates that the TiMs are oblate spheres or fractal aggregates. SEM observations confirm the latter structure. The rationale for differences in modal peak diameter is discussed. © 2016, The Author(s).
Subject
Urban Mobility & Environment
EMS - Environmental Modelling, Sensing & Analysis
ELSS - Earth, Life and Social Sciences
Environment & Sustainability
Environment
Urbanisation
Asymmetric flow field flow fractionation
Inductively coupled plasma mass spectrometry
Nanomaterials
Size distribution
Titanium dioxide
Zirconium
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http://resolver.tudelft.nl/uuid:560dfb13-a771-4c30-abe1-a07bfbb24dad
DOI
https://doi.org/10.1007/s00216-016-9783-6
TNO identifier
572354
ISSN
1618-2642
Source
Analytical and Bioanalytical Chemistry, 408 (24), 6679-6691
Document type
article