Title
Investigation of possible leaching control mechanisms for chromium and vanadium in electric arc furnace (EAF) slags using combined experimental and modeling approaches
Author
Neuhold, S.
van Zomeren, A.
Dijkstra, J.J.
van der Sloot, H.A.
Drissen, P.
Algermissen, D.
Mudersbach, D.
Schüler, S.
Griessacher, T.
Raith, J.G.
Pomberger, R.
Vollprecht, D.
Publication year
2019
Abstract
In this study, possible leaching control mechanisms for Cr and V in electric arc furnace slags were investigated by using a multi-methodological approach. Aside from chemical and mineralogical bulk analyses, special emphasis was given to surface investigations of the slags prior to and after leaching. In addition, pH dependence leaching tests were performed and the obtained data were evaluated with hydrogeochemical models. Investigations revealed that Cr and V are mainly bound in spinel and wuestite as well as minor amounts of olivine. Spinel and wuestite do not dissolve during water leaching for 48 h, whereas, depending on the composition of olivine, this phase either dissolves and releases V and Cr congruently, or does not dissolve but may hydrate. Melilite may also hydrate, but neither V nor Cr were detected in this phase. It appears that leached V is subsequently adsorbed onto these newly hydrated phases. The combination of the applied methods further showed that the abundance of calcium silicates, spinel, and wuestite is influenced by the FeO/SiO2 and CaO/SiO2 ratio in the slag. Therefore, it is assumed that the leaching of V and Cr can be minimized by changing these ratios to favor the formation of Fe bearing calcium silicate and spinel instead of wuestite.
Subject
Energy Efficiency
Energy / Geological Survey Netherlands
To reference this document use:
http://resolver.tudelft.nl/uuid:b735b54d-0a6c-454c-b40e-000ce2faa289
DOI
https://doi.org/10.3390/min9090525
TNO identifier
869719
Publisher
MDPI AG, Basel, Switzerland
ISSN
2075-163X
Source
Minerals, 9 (9)
Article number
525
Document type
article